Textination Newsline

Researchers have developed a method to make adaptive and eco-friendly sensors that can be directly and imperceptibly printed onto a wide range of biological surfaces, whether that’s a finger or a flower petal.

The method, developed by researchers from the University of Cambridge, takes its inspiration from spider silk, which can conform and stick to a range of surfaces. These ‘spider silks’ also incorporate bioelectronics, so that different sensing capabilities can be added to the ‘web’.

The fibres, at least 50 times smaller than a human hair, are so lightweight that the researchers printed them directly onto the fluffy seedhead of a dandelion without collapsing its structure. When printed on human skin, the fibre sensors conform to the skin and expose the sweat pores, so the wearer doesn’t detect their presence. Tests of the fibres printed onto a human finger suggest they could be used as continuous health monitors.

This low-waste and low-emission method for augmenting living structures could be used in a range of fields, from healthcare and virtual reality, to electronic textiles and environmental monitoring. The results are reported in the journal Nature Electronics.

Although human skin is remarkably sensitive, augmenting it with electronic sensors could fundamentally change how we interact with the world around us. For example, sensors printed directly onto the skin could be used for continuous health monitoring, for understanding skin sensations, or could improve the sensation of ‘reality’ in gaming or virtual reality application.

While wearable technologies with embedded sensors, such as smartwatches, are widely available, these devices can be uncomfortable, obtrusive and can inhibit the skin’s intrinsic sensations.

Last year, some of the same researchers showed that if the fibres used in smart textiles were coated with materials that can withstand stretching, they could be compatible with conventional weaving processes. Using this technique, they produced a 46-inch woven demonstrator display.

“If you want to accurately sense anything on a biological surface like skin or a leaf, the interface between the device and the surface is vital,” said Professor Yan Yan Shery Huang from Cambridge’s Department of Engineering, who led the research. “We also want bioelectronics that are completely imperceptible to the user, so they don’t in any way interfere with how the user interacts with the world, and we want them to be sustainable and low waste.”

There are multiple methods for making wearable sensors, but these all have drawbacks. Flexible electronics, for example, are normally printed on plastic films that don’t allow gas or moisture to pass through, so it would be like wrapping your skin in cling film. Other researchers have recently developed flexible electronics that are gas-permeable, like artificial skins, but these still interfere with normal sensation, and rely on energy- and waste-intensive manufacturing techniques.

3D printing is another potential route for bioelectronics since it is less wasteful than other production methods, but leads to thicker devices that can interfere with normal behaviour. Spinning electronic fibres results in devices that are imperceptible to the user, but don't have a high degree of sensitivity or sophistication, and they’re difficult to transfer onto the object in question.

Now, the Cambridge-led team has developed a new way of making high-performance bioelectronics that can be customised to a wide range of biological surfaces, from a fingertip to the fluffy seedhead of a dandelion, by printing them directly onto that surface. Their technique takes its inspiration in part from spiders, who create sophisticated and strong web structures adapted to their environment, using minimal material.

The researchers spun their bioelectronic ‘spider silk’ from PEDOT:PSS (a biocompatible conducting polymer), hyaluronic acid and polyethylene oxide. The high-performance fibres were produced from water-based solution at room temperature, which enabled the researchers to control the ‘spinnability’ of the fibres. The researchers then designed an orbital spinning approach to allow the fibres to morph to living surfaces, even down to microstructures such as fingerprints.

Tests of the bioelectronic fibres, on surfaces including human fingers and dandelion seedheads, showed that they provided high-quality sensor performance while being imperceptible to the host.

“Our spinning approach allows the bioelectronic fibres to follow the anatomy of different shapes, at both the micro and macro scale, without the need for any image recognition,” said Andy Wang, the first author of the paper. “It opens up a whole different angle in terms of how sustainable electronics and sensors can be made. It’s a much easier way to produce large area sensors.”

Most high-resolution sensors are made in an industrial cleanroom and require the use of toxic chemicals in a multi-step and energy-intensive fabrication process. The Cambridge-developed sensors can be made anywhere and use a tiny fraction of the energy that regular sensors require.

The bioelectronic fibres, which are repairable, can be simply washed away when they have reached the end of their useful lifetime, and generate less than a single milligram of waste: by comparison, a typical single load of laundry produces between 600 and 1500 milligrams of fibre waste.

“Using our simple fabrication technique, we can put sensors almost anywhere and repair them where and when they need it, without needing a big printing machine or a centralised manufacturing facility,” said Huang. “These sensors can be made on-demand, right where they’re needed, and produce minimal waste and emissions.”

The research was supported in part by the European Research Council, Wellcome, the Royal Society, and the Biotechnology and Biological Sciences Research Council (BBSRC), part of UK Research and Innovation (UKRI).

Researchers have developed next-generation smart textiles – incorporating LEDs, sensors, energy harvesting, and storage – that can be produced inexpensively, in any shape or size, using conventional industrial looms used to make the clothing worn every day.
 
An international team, led by the University of Cambridge, have previously demonstrated that woven displays can be made at large sizes, but these earlier examples were made using specialised manual laboratory equipment. Other smart textiles can be manufactured in specialised microelectronic fabrication facilities, but these are highly expensive and produce large volumes of waste.

However, the team found that flexible displays and smart fabrics can be made much more cheaply, and more sustainably, by weaving electronic, optoelectronic, sensing and energy fibre components on the same industrial looms used to make conventional textiles. Their results, reported in the journal Science Advances, demonstrate how smart textiles could be an alternative to larger electronics in sectors including automotive, electronics, fashion and construction.

Despite recent progress in the development of smart textiles, their functionality, dimensions and shapes have been limited by current manufacturing processes.
“We could make these textiles in specialised microelectronics facilities, but these require billions of pounds of investment,” said Dr Sanghyo Lee from Cambridge’s Department of Engineering, the paper’s first author. “In addition, manufacturing smart textiles in this way is highly limited, since everything has to be made on the same rigid wafers used to make integrated circuits, so the maximum size we can get is about 30 centimetres in diameter.”

“Smart textiles have also been limited by their lack of practicality,” said Dr Luigi Occhipinti, also from the Department of Engineering, who co-led the research. “You think of the sort of bending, stretching and folding that normal fabrics have to withstand, and it’s been a challenge to incorporate that same durability into smart textiles.”
Last year, some of the same researchers showed that if the fibres used in smart textiles were coated with materials that can withstand stretching, they could be compatible with conventional weaving processes. Using this technique, they produced a 46-inch woven demonstrator display.

Now, the researchers have shown that smart textiles can be made using automated processes, with no limits on their size or shape. Multiple types of fibre devices, including energy storage devices, light-emitting diodes, and transistors were fabricated, encapsulated, and mixed with conventional fibres, either synthetic or natural, to build smart textiles by automated weaving. The fibre devices were interconnected by an automated laser welding method with electrically conductive adhesive.
 
The processes were all optimised to minimise damage to the electronic components, which in turn made the smart textiles durable enough to withstand the stretching of an industrial weaving machine. The encapsulation method was developed to consider the functionality of the fibre devices, and the mechanical force and thermal energy were investigated systematically to achieve automated weaving and laser-based interconnection, respectively.

The research team, working in partnership with textile manufacturers, were able to produce test patches of smart textiles of roughly 50x50 centimetres, although this can be scaled up to larger dimensions and produced in large volumes.
 
“These companies have well-established manufacturing lines with high throughput fibre extruders and large weaving machines that can weave a metre square of textiles automatically,” said Lee. “So when we introduce the smart fibres to the process, the result is basically an electronic system that is manufactured exactly the same way other textiles are manufactured.”
The researchers say it could be possible for large, flexible displays and monitors to be made on industrial looms, rather than in specialised electronics manufacturing facilities, which would make them far cheaper to produce. Further optimisation of the process is needed, however.

“The flexibility of these textiles is absolutely amazing,” said Occhipinti. “Not just in terms of their mechanical flexibility, but the flexibility of the approach, and to deploy sustainable and eco-friendly electronics manufacturing platforms that contribute to the reduction of carbon emissions and enable real applications of smart textiles in buildings, car interiors and clothing. Our approach is quite unique in that way.”

The research was supported in part by the European Union and UK Research and Innovation.